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Sources of Anthropogenic Platinum-Group Elements (PGE): Automotive Catalysts versus PGE-Processing Industries Fathi Zereini; Friso Dirksen; Bernd Skerstupp; Hans Urban Corresponding author:: Dr. Fathi Zereini, Institut für Mineralogie, Johann Wolfgang Goethe-Universität, Georg-Voigt-Straße 16, D-60054 Frankfurt am Main, Germany
Soil samples from the area of Hanau (Hessen, Germany) were analyzed for anthropogenic platinum-group elements (PGE). The results confirm the existence of two different sources for anthropogenic PGE: 1. automotive catalysts, and 2. PGE-processing plants. Both sources emit qualitatively and quantitatively different PGE spectra and PGE interelemental ratios (especially the Pt/Rh ratio). Elevated PGE values which are due to automotive catalysts are restricted to a narrow-range along roadside soil, whereas those due to PGE-processing plants display a large-area dispersion. The emitted PGE-containing particles in the case of automotive catalysts are subject to transport by wind and water, whereas those from PGE-processing plants are preferably transported by wind. This points to a different aerodynamic particle size. Pt, Pd, and Rh concentrations along motorways are dependent on the amount of traffic and the driving characteristics. | | Keywords: automotive catalysts; catalysts, Pt, Pd, Rh; palladium; PGE, anthropogenic sources; PGE, platinum group elements; PGE-processing industries; platinum; platinum group elements (PGE); rhodium |
5 ESPR (4) 223-230 (1998)
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